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Effect of heavy-ion on frequency selectivity of semiconducting polymer/electrolyte heterojunction
Ist Teil von
RSC advances, 2015-01, Vol.5 (119), p.9811-98117
Erscheinungsjahr
2015
Link zum Volltext
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
Heavy ion Nd
3+
is introduced into the electrolyte layer to study frequency selectivity of a semiconducting polymer/electrolyte double-layer cell. This cell exhibits long-term depression under low-frequency stimulations and potentiation under high-frequency stimulations by positive triangular pulses, suggesting a conventional learning protocol,
i.e.
, spike-rate-dependent plasticity. The frequency selectivity depends significantly on the input shape due to large ionic size and mass. The input threshold of the frequency selectivity is around the voltage inducing a negative differential resistance (
V
NDR
) influenced by the loading rate. The typical value of
V
NDR
is 0.3 V for a loading rate of 100 V s
−1
, but
V
NDR
disappears when the loading rate exceeds 1000 V s
−1
. Besides, the frequency selectivity has not been observed under rectangular pulse input. Moreover, the possibility of bidirectional signal transfer has been tested simply by anti-connecting two individual cells. Our study suggests the possibility to realize signal pruning and synthetizing by changing ionic types.
Long-term bidirectional frequency selectivity has been achieved in MEH-PPV/PEO-Nd
3+
cells, which suggests spike-rate-dependent plasticity learning protocol. It depends on pulse shape due to variation of ionic type.