Details

Autor(en) / Beteiligte

• Jia, Bao-Rui
• Qin, Ming-Li
• Zhang, Zi-Li
• Li, Shu-Mei
• Zhang, De-Yin
• Wu, Hao-Yang
• Zhang, Lin
• Lu, Xin
• Qu, Xuan-Hui

Titel

Hollow Porous VOx/C Nanoscrolls as High-Performance Anodes for Lithium-Ion Batteries

Ist Teil von

• ACS applied materials & interfaces, 2016-10, Vol.8 (39), p.25954-25961

Erscheinungsjahr

2016

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Novel hollow porous VOx/C nanoscrolls are synthesized by an annealing process with the VOx/octadecylamine (ODA) nanoscrolls as both vanadium and carbon sources. In the preparation, the VOx/ODA nanoscrolls are first achieved by a two-phase solvothermal method using ammonium metavanadat as the precursor. Upon subsequent heating, the intercalated amines between the vanadate layers in the VOx/ODA nanoscrolls decompose into gases, which escape from inside the nanoscrolls and leave sufficient pores in the walls. As the anodes of lithium-ion batteries (LIBs), such hollow porous VOx/C nanoscrolls possess exceedingly high capacity and rate capability (904 mAh g-1 at 1 A g-1) and long cyclic stability (872 mAh g-1 after 210 cycles at 1 A g-1). The good performance is derived from the unique structural features of the hollow hierarchical porous nanoscrolls with low crystallinity, which could significantly suppress irreversible Li+ trapping as well as improve Li+ diffusion kinetics. This universal method of annealing amine-intercalated oxide could be widely applied to the fabrication of a variety of porous electrode materials for high-performance LIBs and supercapacitors.