Details

Autor(en) / Beteiligte

• Rao, Yutao
• Kim, Jun Oh
• Kim, Woojae
• Zhong, Guangming
• Yin, Bangshao
• Zhou, Mingbo
• Shinokubo, Hiroshi
• Aratani, Naoki
• Tanaka, Takayuki
• Liu, Shubin
• Osuka, Atsuhiro
• Kim, Dongho
• Song, Jianxin

Titel

β-to-β 2,5-Pyrrolylene-Linked Cyclic Porphyrin Oligomers

Ist Teil von

• Chemistry : a European journal, 2016-06, Vol.22 (26), p.8801-8804

Ort / Verlag

Germany: Blackwell Publishing Ltd

Erscheinungsjahr

2016

Quelle

Wiley Online Library - AutoHoldings Journals

Beschreibungen/Notizen

• β‐to‐β 2,5‐Pyrrolylene linked cyclic porphyrin oligomers have been synthesized by Suzuki–Miyaura coupling of 2,5‐diborylpyrrole and 3,7‐dibromoporphyrin. The cyclic porphyrin oligomers exhibit roughly coplanar structures, strong excitonic coupling, small electrochemical HOMO–LUMO gaps, and ultrafast excitation energy transfer between the neighboring porphyrins via the pyrrolylene bridge. Cyclic porphyrin oligomers, formed by β‐to‐β linking with 2,5‐pyrrolylene, have been synthesized by Suzuki–Miyaura coupling of 2,5‐diborylpyrrole and 3,7‐dibromoporphyrin. The cyclic porphyrin oligomers (trimer shown in picture; N blue, Ni green) exhibit roughly coplanar structures, strong excitonic coupling, small electrochemical HOMO–LUMO gaps, and ultrafast excitation energy transfer between the neighboring porphyrins via the pyrrolylene bridge.