Details

Autor(en) / Beteiligte

• Gupta, Sandeep K
• Rajeshkumar, Thayalan
• Rajaraman, Gopalan
• Murugavel, Ramaswamy

Titel

An unprecedented zero field neodymium(iii) single-ion magnet based on a phosphonic diamide

Ist Teil von

• Chemical communications (Cambridge, England), 2016-01, Vol.52 (44), p.7168-7171

Ort / Verlag

England

Erscheinungsjahr

2016

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The axial ligation by the -P[double bond, length as m-dash]O group of a phosphonic diamide in an air-stable Nd(iii) complex ensures a pseudo-D5h symmetry leading to the stabilization of the mJ = |±9/2〉 state; this in turn is responsible for the observed SIM behaviour at zero field and the slow relaxation of magnetization up to 8.0 K.