Chemical communications (Cambridge, England), 2016-01, Vol.52 (38), p.6371-6374
2016
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Details
- Autor(en) / Beteiligte
- Titel
- Operationally simple hydrotrifluoromethylation of alkenes with sodium triflinate enabled by Ir photoredox catalysis
- Ist Teil von
- Chemical communications (Cambridge, England), 2016-01, Vol.52 (38), p.6371-6374
- Ort / Verlag
- England
- Erscheinungsjahr
- 2016
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- We report herein a single component Ir photoredox catalyst which is capable of catalyzing the hydrotrifluoromethylation of terminal alkenes and Michael acceptors with sodium triflinate (Langlois reagent) in methanol under irradiation at room temperature. Various synthetically useful functional groups, including ester, amide, ether, aldehyde, sulfone, ketone and aryl boronate, are well tolerated in this reaction.