Details

Autor(en) / Beteiligte

• Esteruelas, Miguel A
• López, Ana M
• Oliván, Montserrat

Titel

Polyhydrides of Platinum Group Metals: Nonclassical Interactions and σ‑Bond Activation Reactions

Ist Teil von

• Chemical reviews, 2016-08, Vol.116 (15), p.8770-8847

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2016

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The preparation, structure, dynamic behavior in solution, and reactivity of polyhydride complexes of platinum group metals, described during the last three decades, are contextualized from both organometallic and coordination chemistry points of view. These compounds, which contain dihydrogen, elongated dihydrogen, compressed dihydride, and classical dihydride ligands promote the activation of B–H, C–H, Si–H, N–H, O–H, C–C, C–N, and C–F, among other σ-bonds. In this review, it is shown that, unlike other more mature areas, the chemistry of polyhydrides offers new exciting conceptual challenges and at the same time the possibility of interacting with other fields including the conversion and storage of regenerative energy, organic synthetic chemistry, drug design, and material science. This wide range of possible interactions foresees promising advances in the near future.