Soft matter, 2016-03, Vol.12 (12), p.2997-3003
2016
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Details
- Autor(en) / Beteiligte
- Titel
- Anion triggered metallogels: demetalation and crystal growth inside the gel matrix and improvement in viscoelastic properties using Au-NPs
- Ist Teil von
- Soft matter, 2016-03, Vol.12 (12), p.2997-3003
- Ort / Verlag
- England
- Erscheinungsjahr
- 2016
- Quelle
- MEDLINE
- Beschreibungen/Notizen
- Progelator complex Zn-TRPA-2 undergoes Cl(-) triggered gelation to afford ZTP2G, while Zn-TRPA-2 capped Au-NPs under similar conditions gave another gel GNZTP2G which also represents a rare nano-composite metallogel. When Zn-TRPA-2 was triggered by Cl(-) and NO3(-) simultaneously, crystals of demetalated species NA-TRPA-2 grew inside the ZTP2G matrix. Interestingly, GNZTP2G exhibits superior viscoelastic properties over ZTP2G.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1744-683XeISSN: 1744-6848DOI: 10.1039/c5sm02464aTitel-ID: cdi_proquest_miscellaneous_1800502682
- Format
- –
- Schlagworte
- Anions, Anions - chemistry, Capping, Coordination Complexes - chemistry, Crystal growth, Crystallization, Crystals, Elasticity, Gelation, Gels - chemistry, Gold - chemistry, Metal Nanoparticles - chemistry, Microscopy, Atomic Force, Microscopy, Electron, Scanning, Microscopy, Electron, Transmission, Nanostructure, Viscoelasticity, Viscosity, Zinc, Zinc - chemistry