Details

Autor(en) / Beteiligte

• Xu, Mei-Yu
• Wang, Ya-Ting
• Ni, Qing-Ling
• Zhang, Zi-Hao
• Wang, Xiu-Jian
• Liang, Guang-Ming
• Gui, Liu-Cheng

Titel

Aggregation of the metallocycles {Cu sub(8)} and {Cu sub(20)} using [Cu(bp)] units (H sub(2)bp = bis(2-hydroxybenzyl)amine): structures and magnetic properties

Ist Teil von

• Dalton transactions : an international journal of inorganic chemistry, 2016-03, Vol.45 (12), p.4993-4997

Erscheinungsjahr

2016

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Two metallocycles, {Cu sub(8)(bp) sub(4)(OH) sub(4)(H sub(2)O) sub(4) (ClO sub(4)) sub(4)} (1) and {Cu sub(20)(bp) sub(20)} (2), were afforded by the reactions of the semi-flexible tridentate ligand bis(2-hydroxybenzyl)amine (H sub(2)bp) with Cu(ClO sub(4)) sub(2).6H sub(2)O and Cu(OAc) sub(2).H sub(2)O. Complex 1 has a saddle-shaped cyclic structure and complex 2 has a nanosized wheel-shaped structure. The two compounds consist of [Cu(bp)] units.