Details

Autor(en) / Beteiligte

• Xia, Yun-Fei
• Nie, Min
• Wang, Zhen-Bo
• Yu, Fu-Da
• Zhang, Yin
• Zheng, Li-Li
• Wu, Jin
• Ke, Ke

Titel

Structural, morphological and electrochemical investigation of LiNi0.6Co0.2Mn0.2O2 cathode material synthesized in different sintering conditions

Ist Teil von

• Ceramics international, 2015-11, Vol.41 (9), p.11815-11823

Ort / Verlag

Elsevier Ltd

Erscheinungsjahr

2015

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Layered structure LiNi0.6Co0.2Mn0.2O2 cathode material was synthesized via a two-step solid state reaction with industrial Ni0.6Co0.2Mn0.2(OH)2 and Li2CO3 in this paper. The samples prepared at different sintering temperatures (750–850°C) and sintering times (10–18h) were analyzed by physical and electrochemical methods to gain the optimal sintering condition, and an additional XRD Rietveld refinement was taken to get more reliable structural parameters. The results demonstrated that the higher temperature leads to larger primary particle size and severer agglomeration, while duration factor may affect the electrochemical performance rather than the structure and morphology of the materials. The optimized NCM622 material has an initial discharge capacity of 156.3mAhg−1 at 1C, whose capacity retention even reached 102.9% after 100 cycles. In addition, the three dispersed peaks (P1, P2, P3) in particle distribution analysis and RSEI, Re, Rct in electrochemical impedance spectroscopy have been separated and discussed in detail.