Details

Autor(en) / Beteiligte

• Yang, Kai
• Song, Qiuling

Titel

Transition-metal-free regioselective synthesis of alkylboronates from arylacetylenes and vinyl arenes

Ist Teil von

• Green chemistry : an international journal and green chemistry resource : GC, 2016-01, Vol.18 (4), p.932-936

Erscheinungsjahr

2016

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A transition-metal-free synthesis of alkylboronates, utilizing arylacetylenes or vinyl arenes and bis(pinacolato)diboron through tandem borylation and protodeboronation, has been developed. This reaction is efficient, practical and environmentally benign, leading to anti-Markovnikov products with excellent regioselectivity, broad functional group tolerance and excellent yields in both small and gram scales.