Details

Autor(en) / Beteiligte

• van Dijk, Tom
• Burck, Sebastian
• Rosenthal, Amos J.
• Nieger, Martin
• Ehlers, Andreas W.
• Slootweg, J. Chris
• Lammertsma, Koop

Titel

Synthesis and Coordination Chemistry of Iminophosphanes

Ist Teil von

• Chemistry : a European journal, 2015-06, Vol.21 (26), p.9328-9331

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2015

Quelle

Wiley Online Library All Journals

Beschreibungen/Notizen

• Iminophosphanes are a new group of 1,3‐P,N‐ligands, readily obtainable from secondary phosphanes and nitrilium ions, having a tunable N‐donor site by means of varying the imine substituents. These ligands give, in high yields, monodentate gold complexes and bidentate rhodium and iridium complexes. Crystal structures are reported for both the ligands and the complexes. Know what imino? Iminophosphanes are a new group of tunable 1,3‐P,N‐ligands, readily obtained from secondary phosphanes and nitrilium ions. They produce, in high yields, monodentate gold complexes and bidentate rhodium and iridium complexes.