Sie befinden Sich nicht im Netzwerk der Universität Paderborn. Der Zugriff auf elektronische Ressourcen ist gegebenenfalls nur via VPN oder Shibboleth (DFN-AAI) möglich. mehr Informationen...
Platinum Group Metal Clusters: From Gas-Phase Structures and Reactivities towards Model Catalysts
Ist Teil von
Chemistry : a European journal, 2014-03, Vol.20 (12), p.3258-3267
Ort / Verlag
Weinheim: WILEY-VCH Verlag
Erscheinungsjahr
2014
Quelle
Wiley-Blackwell Journals
Beschreibungen/Notizen
Transition‐metal clusters have long been proposed as model systems to study heterogeneous catalysts. In this Concept article we show how advanced spectroscopic techniques can be used to determine the structures of gas‐phase transition‐metal clusters and their complexes with small molecules. Combined with computational studies, this can help to develop an understanding of the reactivity of these catalytic models.
Caught in the act: Transition‐metal clusters have long been proposed as model systems to study heterogeneous catalysts. This Concept article shows how advanced spectroscopic techniques can be used to investigate gas‐phase metal clusters and their complexes with small molecules, with the aim of developing an understanding of their reactivity (see figure).