Details

Autor(en) / Beteiligte

• Jurado, Anna
• Mastroianni, Nicola
• Vàzquez-Suñé, Enric
• Carrera, Jesus
• Tubau, Isabel
• Pujades, Estanislao
• Postigo, Cristina
• de Alda, Miren López
• Barceló, Damià

Titel

Drugs of abuse in urban groundwater. A case study: Barcelona

Ist Teil von

• The Science of the total environment, 2012-05, Vol.424, p.280-288

Ort / Verlag

Kidlington: Elsevier B.V

Erscheinungsjahr

2012

Link zum Volltext

Quelle

MEDLINE

Beschreibungen/Notizen

• This study is concerned with drugs of abuse (DAs) and their metabolites in urban groundwater at field scale in relation to (1) the spatial distribution of DAs in Barcelona's groundwater, (2) the depth of the groundwater samples, (3) the presence of DAs in recharge sources, and (4) the assessment of the fate of DAs in Barcelona aquifers. To this end, 37 urban groundwater samples were collected in the city of Barcelona and a total of 21 drugs were analyzed including cocainics, amphetamine-like compounds, opioids, lysergics and cannabinoids and the prescribed drugs benzodiazepines. Overall, the highest groundwater concentrations (around 200ng/L in SAP-4) and the largest number of detected DAs were found in zones basically recharged by a river that receives large amounts of effluents from waste water treatment plants (WWTPs). In contrast, the urbanized areas yielded not only lower concentrations but also a much smaller number of drugs, which suggests a local origin. In fact, cocaine and its metabolite were dominant in more prosperous neighborhoods, whereas the cheaper MDMA was the dominant DA in poorer districts. Measured concentrations were consistently smaller than those estimated from the waste water fraction in groundwater samples, suggesting that DAs undergo removal processes in both reducing and oxidizing conditions. ► Urban groundwater contamination by drugs of abuse (DAs). ► DAs in urban groundwater were detected in levels of nanograms per liter. ► The largest number of DAs were found when the aquifer is recharged by a river. ► DAs undergo removal processes in the aquifer under different redox conditions.