Details

Autor(en) / Beteiligte

• Shi, S.J.
• Tu, J.P.
• Tang, Y.Y.
• Liu, X.Y.
• Zhang, Y.Q.
• Wang, X.L.
• Gu, C.D.

Titel

Enhanced cycling stability of Li[Li0.2Mn0.54Ni0.13Co0.13]O2 by surface modification of MgO with melting impregnation method

Ist Teil von

• Electrochimica acta, 2013-01, Vol.88, p.671-679

Ort / Verlag

Kidlington: Elsevier Ltd

Erscheinungsjahr

2013

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• ► MgO is well coated on Li[Li0.2Mn0.54Ni0.13Co0.13]O2 by melting impregnation method. ► The 2wt.% coated sample exhibits initial capacity of 260.8mAhg−1 at 0.1C. ► Capacity retention of 96.4% is obtained at 1C (200mAg−1) after 100 cycles at 25°C. ► 94.3% of capacity is retained after 50 cycles at 1C after 50 cycles at 60°C. MgO-coated Li[Li0.2Mn0.54Ni0.13Co0.13]O2 was synthesized via melting impregnation method followed by a solid state reaction. Transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) show that the MgO layer is well coated on the surface of the layered oxide particles. Although the initial discharge capacity of Li[Li0.2Mn0.54Ni0.13Co0.13]O2 with proper MgO modification decreases compared to the bare one, the 2wt.% MgO coated cathode exhibits the excellent cycling stability with capacity retention of 96.4% at a current density of 200mAg−1 after 100 cycles at room temperature and 94.3% after 50 cycles at 60°C. Electrochemical impedance spectroscopy (EIS) shows that the thin MgO layer mainly reduces the charge transfer resistance and stabilizes the surface structure of active material during cycling. Melting impregnation method is promising for MgO coating to improving the cycling stability of Li-rich layered oxide cathode for Li-ion batteries.