Details

Autor(en) / Beteiligte

• Capobianco, Amedeo
• Caruso, Tonino
• D’Ursi, Anna Maria
• Fusco, Sandra
• Masi, Annalisa
• Scrima, Mario
• Chatgilialoglu, Chryssostomos
• Peluso, Andrea

Titel

Delocalized Hole Domains in Guanine-Rich DNA Oligonucleotides

Ist Teil von

• The journal of physical chemistry. B, 2015-04, Vol.119 (17), p.5462-5466

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2015

Quelle

MEDLINE

Beschreibungen/Notizen

• Differential pulse voltammetries of guanine-rich single- and double-stranded oligonucleotides containing up to six consecutive guanines are reported. The observed progressive lowering of the first voltammetric peak potential as the number of adjacent guanines increases unambiguously points toward the establishment of delocalized hole domains; the hole stabilization energy is ca. 0.1 eV per GG step, significantly lower than that observed for AA steps.