Chemical communications (Cambridge, England), 2015-01, Vol.51 (73), p.13914-13917
2015
Volltextzugriff (PDF)
Details
- Autor(en) / Beteiligte
- Titel
- First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands
- Ist Teil von
- Chemical communications (Cambridge, England), 2015-01, Vol.51 (73), p.13914-13917
- Ort / Verlag
- England
- Erscheinungsjahr
- 2015
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium) salt allowed us to obtain the first homoleptic tris-MIC cylinder-like cages of Ag and Au. The silver MIC-based cage reacts with the tris-NHC-Ag analogue to form the corresponding heteroleptic NHC-MIC silver cage in an unusual reaction involving the simultaneous exchange of the tris-NHC and tris-MIC ligands.