Details

Autor(en) / Beteiligte

• Kalkhambkar, Rajesh G.
• Waters, Sarah N.
• Laali, Kenneth K.

Titel

Highly efficient synthesis of amides via Ritter chemistry with ionic liquids

Ist Teil von

• Tetrahedron letters, 2011-02, Vol.52 (8), p.867-871

Ort / Verlag

Elsevier Ltd

Erscheinungsjahr

2011

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The utility of Brønsted-acidic imidazolium ionic liquid [BMIM(SO 3H)][OTf] as catalyst for the high yield synthesis of a wide variety of amides under mild conditions via the Ritter reaction of alcohols with nitriles has been demonstrated. As alternative methods for the carbocation generation step, NOPF 6 immobilized in [BMIM][PF 6] ionic liquid was used in the Ritter reaction of bromides with nitriles and for the synthesis of adamantyl amides from adamantane and nitriles.