Tetrahedron letters, 2011-07, Vol.52 (29), p.3805-3809
2011
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Details
- Autor(en) / Beteiligte
- Titel
- One step synthesis of azo compounds from nitroaromatics and anilines
- Ist Teil von
- Tetrahedron letters, 2011-07, Vol.52 (29), p.3805-3809
- Ort / Verlag
- Kidlington: Elsevier Ltd
- Erscheinungsjahr
- 2011
- Quelle
- Access via ScienceDirect (Elsevier)
- Beschreibungen/Notizen
- The method for synthesis of both symmetric and asymmetric aromatic azo compounds without metal has been developed in one single step. The electronic effect and substituent effect of the compounds have been discussed. A general and efficient method for synthesis of both symmetric and asymmetric aromatic azo compounds in one single step has been developed. The nitro compounds were reduced and the substituted anilines were oxidized by each other without any metal in the base condition. Various azo compounds with halogen, methyl and methoxy functional group were obtained by using available, cheap nitro compounds and substituted anilines. In addition, the electronic effect and substituent effect of the compounds have been discussed.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 0040-4039eISSN: 1873-3581DOI: 10.1016/j.tetlet.2011.05.054Titel-ID: cdi_proquest_miscellaneous_1744676953
- Format
- –
- Schlagworte
- Aniline, Aromatic azo compound, Asymmetric, Asymmetry, Azo compounds, Chemistry, Electronics, Exact sciences and technology, Halogens, Nitro compounds, Noncondensed benzenic compounds, Organic chemistry, Preparations and properties, Redox reaction, Synthesis (chemistry), Tetrahedrons