Details

Autor(en) / Beteiligte

• Schneider, Alexandre B.
• Nascimento, Paulo C.
• Bohrer, Denise
• de Carvalho, Leandro M.
• Guarda, Ananda
• Krause, Cristian
• Wiethan, Bruna A.
• Koschinsky, Andrea

Titel

Determination of Zirconium and Vanadium in Natural Waters by Adsorptive Stripping Voltammetry in the Presence of Cupferron, Oxalic Acid and 1,3-Diphenylguanidine

Ist Teil von

• Electroanalysis (New York, N.Y.), 2015-08, Vol.27 (8), p.1864-1870

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2015

Quelle

Wiley-Blackwell Journals

Beschreibungen/Notizen

• A sequential AdSV method based on the accumulation of Zr(IV) and V(V) as cupferron‐oxalic acid‐1,3‐diphenylguanidine (COD) complexes at the HMDE was used to determine traces of these metals in samples with different ionic strengths. DP mode, Eads −0.6 and −0.2 V (vs. Ag/AgCl, 3 mol L−1 KCl), tads 400 and 20 s and 10 and 60 mV s−1 scan rates were used for Zr(IV) and V(V), respectively. Epeak were −0.95 (Zr(IV)‐COD) and −0.65 V(V(V)‐COD). The methodology was applied in samples of rivers, estuaries (in Germany and Brazil) and coastal and open seawater.