RSC advances, 2014-01, Vol.4 (40), p.20632-20635
2014
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Details
- Autor(en) / Beteiligte
- Titel
- A Ru-catalyzed one-pot synthesis of homopropargylic amines from alkyl azides under photolytic conditions
- Ist Teil von
- RSC advances, 2014-01, Vol.4 (40), p.20632-20635
- Erscheinungsjahr
- 2014
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- A new synthetic method for homopropargylic amines from alkyl azides is presented. A salient feature of this reaction is the involvement of N -unsubstituted imines as the key intermediates, which are generated from alkyl azides by Ru catalysis under photolytic conditions. Notably, this method avoids the use of a protective group strategy in the homopropargylic amine synthesis.