Details

Autor(en) / Beteiligte

• Lin, Wei-Chi
• Hu, Jiun-Wei
• Chen, Kew-Yu

Titel

A ratiometric chemodosimeter for highly selective naked-eye and fluorogenic detection of cyanide

Ist Teil von

• Analytica chimica acta, 2015-09, Vol.893, p.91-100

Ort / Verlag

Netherlands: Elsevier B.V

Erscheinungsjahr

2015

Quelle

MEDLINE

Beschreibungen/Notizen

• A simple indole-based chemosensor (1) with a very low molecular weight of 207 g mol−1 has been synthesized for the highly reactive and selective detection of CN− in aqueous media, even in the presence of other anions, such as F−, Cl−, Br−, AcO−, S2−, SCN−, NO2−, NO3−, CO3−, BzO−, H2PO4−, and HSO4−. The sensor achieves rapid detection of cyanide anion in 2 min, and the pseudo-first-order rate constant is estimated as 1.576 min−1. The colorimetric and ratiometric fluorescent response of the sensor to CN− is attributable to the addition of CN− to the electron-deficient dicyanovinyl group of 1, which prevents intramolecular charge transfer. The sensing mechanism is supported by density functional theory and time-dependent density functional theory calculations. Moreover, sensor 1 exhibits both high accuracy in determining the concentration of CN− in real samples and 1-based test strips can conveniently detect CN− without any additional equipment. The detection limit of the sensor 1 (1.1 μM) for cyanide is lower than the maximum permissible level of CN− (1.9 μM) in drinking water. [Display omitted] •A simple indole-based chemodosimeter specific for CN− has been developed.•The sensor exhibits colorimetric and ratiometric fluorescent response to CN−.•An ESICT mechanism plays a key role in the sensing properties.