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Mechanism of volume shrinkage during reaction between Ni and Ag-doped Sn
Ist Teil von
Materials letters, 2015-10, Vol.156, p.150-152
Ort / Verlag
Elsevier B.V
Erscheinungsjahr
2015
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
The volume shrinkage during the solid-state reaction in Ag-doped Sn micro-joints for three-dimensional integrated-circuit applications is measured. It is found that more than 94% of the volume shrinkage is accommodated by height reduction of the micro-joints. This observation is in sharp contrast to results of a previous study in which no Ag was added, and the volume shrinkage occurred through both height reduction and void formation. A mechanism that accounts for this difference is proposed.
•With 3.0wt% Ag doping, no micro-voids formed after Sn exhausted.•The volume shrinkage is dissipated only through height reduction for Ag-doped Sn.•The formation of micro-voids of Ni/Sn/Ni is due to the Kirkendall effect.•The larger reduction in joint height might introduce a higher internal stress.