Details

Autor(en) / Beteiligte

• Mao, Zhu
• Yang, Zhiyong
• Mu, Yingxiao
• Zhang, Yi
• Wang, Yi-Fan
• Chi, Zhenguo
• Lo, Chang-Cheng
• Liu, Siwei
• Lien, Alan
• Xu, Jiarui

Titel

Linearly Tunable Emission Colors Obtained from a Fluorescent-Phosphorescent Dual-Emission Compound by Mechanical Stimuli

Ist Teil von

• Angewandte Chemie (International ed.), 2015-05, Vol.54 (21), p.6270-6273

Auflage

International ed. in English

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2015

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Organic mechanoluminochromic materials are mechano/piezo‐responsive and promising for applications in sensors, displays, and data storage devices. However, their switching range of emission is seriously impeded by only one kind of emission (either a fluorescent or phosphorescent peak) in the spectrum of single organic compounds. This study presents a design strategy for pure organic compounds with excellent room‐temperature fluorescent–phosphorescent dual‐emission (rFPDE) properties, which combines the effective factors of dipenylsulfone group, crystalline state, and heavy atom effect. Following the principle of color mixing, myriad emission colors with a wide range from orange to purple and across white zone in a straight line in the chromaticity diagram of the Commission Internationale de l’Eclairage (CIE) can be obtained by simply mechanical grinding the compound. The unique properties could be concentrated on a pure organic compound through this design strategy, which provides a new efficient channel for the discovery of efficient mechano‐responsive organic materials. Grinding a rainbow: A purely organic compound with excellent room‐temperature fluorescent–phosphorescent dual‐emission (rFPDE) properties brought about by mechanical grinding has been demonstrated. It shows linearly tunable emission colors with a straight line across the white zone in the chromaticity diagram, following the principle of color mixing.