Details

Autor(en) / Beteiligte

• Bedford, Robin B.
• Carter, Emma
• Cogswell, Paul M.
• Gower, Nicholas J.
• Haddow, Mairi F.
• Harvey, Jeremy N.
• Murphy, Damien M.
• Neeve, Emily C.
• Nunn, Joshua

Titel

Simplifying Iron-Phosphine Catalysts for Cross-Coupling Reactions

Ist Teil von

• Angewandte Chemie International Edition, 2013-01, Vol.52 (4), p.1285-1288

Auflage

International ed. in English

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2013

Quelle

MEDLINE

Beschreibungen/Notizen

• Any old iron? Iron catalysts based on the widely available diphosphine ligand bis(diphenylphosphino)ethane have not previously fared particularly well in iron‐catalyzed cross‐coupling processes. However, this turns out not to be due to any inherently poor performance associated with the ligand, but rather the need to form a bis‐chelate complex, either before or during the formation of an active FeI species.