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Ultrathin Alternating Copolymer Nanotubes with Readily Tunable Surface Functionalities
Ist Teil von
Angewandte Chemie International Edition, 2015-03, Vol.54 (12), p.3621-3625
Auflage
International ed. in English
Ort / Verlag
Weinheim: WILEY-VCH Verlag
Erscheinungsjahr
2015
Quelle
MEDLINE
Beschreibungen/Notizen
Well‐defined ultrathin nanotubes (30 nm in diameter and of micrometer‐scale length) were generated through the self‐assembly of a novel alternative copolymer synthesized using an epoxy–thiol click‐chemistry reaction. The self‐assembly mechanism was investigated both by experiments and using dissipative particle dynamics (DPD) simulations. The obtained nanotubes can be readily functionalized with carboxy groups, amino groups, peptides, or other groups by simple modular click copolymerization.
Clicking into place: Ultrathin nanotubes with readily tunable surface functionalities self‐assemble from a novel alternative copolymer synthesized using epoxy–thiol click chemistry. The copolymer self‐assembly mechanism is investigated experimentally and using dissipative particle dynamics simulations.