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Details

Autor(en) / Beteiligte
Titel
Solvothermal synthesis of MnFe2O4-graphene composite—Investigation of its adsorption and antimicrobial properties
Ist Teil von
  • Applied surface science, 2015-02, Vol.327, p.27-36
Ort / Verlag
Elsevier B.V
Erscheinungsjahr
2015
Link zum Volltext
Quelle
Elsevier ScienceDirect Journals Complete
Beschreibungen/Notizen
  • •Graphene manganese ferrite composite was synthesized by a solvothermal process.•Adsorption of Pb and Cd metal ions were tested with MnFe2O4-G material.•The MnFe2O4-G material showed good adsorption capacity for metal ions.•MnFe2O4-G showed the higher antibacterial activity of 82%, than graphene. Graphene manganese ferrite (MnFe2O4-G) composite was prepared by a solvothermal process. The as-prepared graphene manganese ferrite composite was tested for the adsorption of lead (Pb(II)) and cadmium (Cd(II)) ions by analytical methods under diverse experimental parameters. With respect to contact time measurements, the adsorption of Pb and Cd ions increased and reached equilibrium within 120 and 180min at 37°C with a maximum adsorption at pH 5 and 7 respectively. The Langmuir model correlates to the experimental data showing an adsorption capacity of 100 for Pb(II) and 76.90mgg−1 for Cd(II) ions. Thermodynamic studies revealed that the adsorption of Pb and Cd ions onto MnFe2O4-G was spontaneous, exothermic and feasible in the range of 27–47°C. Cytotoxicity behavior of graphene against bacterial cell membrane is well known. To better understand its antimicrobial mechanism, the antibacterial activity of graphene and MnFe2O4-G nanocomposite was compared. Under similar concentration and incubation conditions, nanocomposite MnFe2O4-G dispersion showed the highest antibacterial activity of 82%, as compared to graphene showing 37% cell loss. Results showed that the prepared composite possess good adsorption efficiency and thus could be considered as an excellent material for removal of toxic heavy metal ions as explained by adsorption isotherm. Hence MnFe2O4-G can be used as an adsorbent as well as an antimicrobial agent.
Sprache
Englisch
Identifikatoren
ISSN: 0169-4332
eISSN: 1873-5584
DOI: 10.1016/j.apsusc.2014.11.096
Titel-ID: cdi_proquest_miscellaneous_1680449187

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