Details

Autor(en) / Beteiligte

• Li, Gang
• Zhao, Yongbiao
• Li, Junbo
• Cao, Jun
• Zhu, Jia
• Sun, Xiao Wei
• Zhang, Qichun

Titel

Synthesis, Characterization, Physical Properties, and OLED Application of Single BN-Fused Perylene Diimide

Ist Teil von

• Journal of organic chemistry, 2015-01, Vol.80 (1), p.196-203

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2015

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• It is very challenging to introduce azaborine into an electron-deficient arene system because of unfavorable intramolecular electrophilic borylation reaction. In this report, we adopted a straightforward methodology to construct a large BN-embedded π-system based on perylene diimide (PDI), which is the first BN-annulation example with highly electron-withdrawing polycyclic aromatic hydrocarbons. The physical properties of the as-prepared N,N-dicyclohexyl-1-aza-12-bora-benzoperylene diimide (PDI-1BN) have been fully studied, and its sensing behavior to fluoride ion as well as its OLED performance was also investigated.