Details

Autor(en) / Beteiligte

• Gangadhararao, G
• Tulichala, R N Prasad
• Swamy, K C Kumara

Titel

Spontaneous resolution upon crystallization of allenyl-bis-phosphine oxides

Ist Teil von

• Chemical communications (Cambridge, England), 2015-04, Vol.51 (33), p.7168-7171

Ort / Verlag

England

Erscheinungsjahr

2015

Quelle

MEDLINE

Beschreibungen/Notizen

• The first example of 'spontaneous resolution by crystallization' in allene chemistry, by means of crystal structures and solid state CD spectra of the R and S enantiomers, is presented. These allenes are prepared by the simple reaction of Ph2PCl with o-nitro functionalized propargyl alcohols.