Details

Autor(en) / Beteiligte

• ZAMMIT, Elizabeth M
• BARBANTE, Gregory J
• CARLSON, Brenden
• DOEVEN, Egan H
• BARNETT, Neil W
• HOGAN, Conor F
• RICHTER, Mark M
• FRANCIS, Paul S

Titel

Chemiluminescence from osmium(II) complexes with phenanthroline, diphosphine and diarsine ligands

Ist Teil von

• Analyst (London), 2012-06, Vol.137 (12), p.2766-2769

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2012

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The reaction of various [Os(L)(2)(L')](2+) complexes (where L and L' are phenanthroline, diphosphine or diarsine ligands) and organic reducing agents after chemical or electrochemical oxidation of the reactants produces an emission of light corresponding to MLCT transitions. In certain instances, the emission was greater than that of [Ru(bipy)(3)](2+), but the relative signals were dependent on many factors, including reagent concentration, mode of oxidation, reducing agent and the sensitivity of the photodetector over the wavelength range.