Advanced synthesis & catalysis, 2011-01, Vol.353 (1), p.31-35
2011
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Details
- Autor(en) / Beteiligte
- Titel
- Base-Mediated Tandem Reaction Consisting of an Acyl Shift Strategy Leading to 4,5-Disubstiuted Furan-2(5H)-ones
- Ist Teil von
- Advanced synthesis & catalysis, 2011-01, Vol.353 (1), p.31-35
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag
- Erscheinungsjahr
- 2011
- Quelle
- Wiley Online Library
- Beschreibungen/Notizen
- The first example of the synthesis of 4,5‐disubstiuted furan‐2(5H)‐ones by base‐mediated tandem acyl shift/cyclization/decarbonylation reactions of aroylmethyl 2‐alkynoates has been developed. This new and inexpensive tandem route allows both a CO bond and a Csp3Csp2 bond forming in one step involving an unprecedented acyl rearrangement process.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1615-4150, 1615-4169eISSN: 1615-4169DOI: 10.1002/adsc.201000762Titel-ID: cdi_proquest_miscellaneous_1671254833
- Format
- –
- Schlagworte
- acyl shift, base, Bonding, Carbon monoxide, Cascade chemical reactions, Catalysis, Chemistry, cyclization, CC bond formation, decarbonylation, Exact sciences and technology, Forming, furan-2(5H)-ones, Heterocyclic compounds, Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives, Organic chemistry, Preparations and properties, Strategy, Synthesis