Details

Autor(en) / Beteiligte

• Hao, Xin-Hua
• Gao, Pin
• Song, Xian-Rong
• Qiu, Yi-Feng
• Jin, Dong-Po
• Liu, Xue-Yuan
• Liang, Yong-Min

Titel

Metal-free nitro-carbocyclization of 1,6-enynes with (t)BuONO and TEMPO

Ist Teil von

• Chemical communications (Cambridge, England), 2015-04, Vol.51 (31), p.6839-6842

Ort / Verlag

England

Erscheinungsjahr

2015

Quelle

MEDLINE

Beschreibungen/Notizen

• A novel and convenient metal-free nitration and cyclization of 1,6-enynes has been developed. Two C-C bonds and one C-N bond were constructed in one process in this reaction. This transformation is proven to have relatively good functional-group applicability and can be scaled up to gram quantities in satisfactory yields. According to the following experimental facts and related literature reports, a radical pathway was involved in this transformation.