Details

Autor(en) / Beteiligte

• Mihaylov, Mihail Y
• Ivanova, Elena Z
• Aleksandrov, Hristiyan A
• St Petkov, Petko
• Vayssilov, Georgi N
• Hadjiivanov, Konstantin I

Titel

Formation of N3(-) during interaction of NO with reduced ceria

Ist Teil von

• Chemical communications (Cambridge, England), 2015-04, Vol.51 (26), p.5668-5671

Ort / Verlag

England

Erscheinungsjahr

2015

Quelle

MEDLINE

Beschreibungen/Notizen

• We show that the first stages of interaction between NO and reduced ceria comprise the formation of azides, N3(-), with simultaneous oxidation of Ce(3+) to Ce(4+). This finding imposes revision on some current views of catalytic NO conversion and may contribute to design of new deNOx materials and processes.