Details

Autor(en) / Beteiligte

• McDanel, William M.
• Cowan, Matthew G.
• Carlisle, Trevor K.
• Swanson, Anna K.
• Noble, Richard D.
• Gin, Douglas L.

Titel

Cross-linked ionic resins and gels from epoxide-functionalized imidazolium ionic liquid monomers

Ist Teil von

• Polymer (Guilford), 2014-08, Vol.55 (16), p.3305-3313

Ort / Verlag

Elsevier Ltd

Erscheinungsjahr

2014

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A novel bis(epoxide)-functionalized ionic liquid (IL) monomer has been reacted with a commercially available amine monomer to produce cross-linked, epoxy-amine-based poly(ionic liquid) (PIL) resins and PIL/IL ion-gels via step-growth (S-G) polymerization. The degree of chemical functionality was controlled by manipulating the monomer stoichiometric ratios. The S-G PIL resins were investigated for CO2 sorption and have a relatively high equilibrium loading of 1.0 mmol CO2/(g resin). PIL/IL ion-gel membranes were subsequently prepared and tested for CO2/light gas permeation. These materials have CO2/N2 and CO2/CH4 permselectivity values near the Robeson upper bound. Analysis of their gas permeation data revealed that these materials exhibit a rare case of inverse CO2/CH4 diffusion selectivity (DCO2/DCH4<1). This phenomenon was attributed to the interaction of CO2 with residual and formed amine groups in the S-G PIL, resulting in a low CO2 diffusivity compared to that of non-interacting CH4. [Display omitted]