Sie befinden Sich nicht im Netzwerk der Universität Paderborn. Der Zugriff auf elektronische Ressourcen ist gegebenenfalls nur via VPN oder Shibboleth (DFN-AAI) möglich. mehr Informationen...
Retarding the corrosion of iron by inhomogeneous magnetic fields
Ist Teil von
Materials and corrosion, 2014-08, Vol.65 (8), p.803-808
Ort / Verlag
Weinheim: Blackwell Publishing Ltd
Erscheinungsjahr
2014
Link zum Volltext
Quelle
Wiley-Blackwell Journals
Beschreibungen/Notizen
The influence of a magnetic field yielding high magnetic flux densities and high flux density gradients on the free corrosion behavior of iron in a low concentrated acidic solution with and without chloride ions is studied by long time exposure experiments and electrochemical impedance spectroscopy (EIS). A decrease of the corrosion rate in electrode surface regions of high magnetic flux density is detected. This decrease of the dissolution rate is significantly stronger in the presence of chloride ions. The observed effects are discussed on the basis of the magnetically induced forces acting on the ions present in the solution, the surface coverage fraction of adsorbed species, and the stability of these adsorbed species.