Details

Autor(en) / Beteiligte

• Hao, Yufeng
• Bharathi, M. S.
• Wang, Lei
• Liu, Yuanyue
• Chen, Hua
• Nie, Shu
• Wang, Xiaohan
• Chou, Harry
• Tan, Cheng
• Fallahazad, Babak
• Ramanarayan, H.
• Magnuson, Carl W.
• Tutuc, Emanuel
• Yakobson, Boris I.
• McCarty, Kevin F.
• Zhang, Yong-Wei
• Kim, Philip
• Hone, James
• Colombo, Luigi
• Ruoff, Rodney S.

Titel

The Role of Surface Oxygen in the Growth of Large Single-Crystal Graphene on Copper

Ist Teil von

• Science (American Association for the Advancement of Science), 2013-11, Vol.342 (6159), p.720-723

Ort / Verlag

Washington, DC: American Association for the Advancement of Science

Erscheinungsjahr

2013

Quelle

Science Online_科学在线

Beschreibungen/Notizen

• The growth of high-quality single crystals of graphene by chemical vapor deposition on copper (Cu) has not always achieved control over domain size and morphology, and the results vary from lab to lab under presumably similar growth conditions. We discovered that oxygen (O) on the Cu surface substantially decreased the graphene nucleation density by passivating Cu surface active sites. Control of surface O enabled repeatable growth of centimeter-scale single-crystal graphene domains. Oxygen also accelerated graphene domain growth and shifted the growth kinetics from edge-attachment-limited to diffusion-limited. Correspondingly, the compact graphene domain shapes became dendritic. The electrical quality of the graphene films was equivalent to that of mechanically exfoliated graphene, in spite of being grown in the presence of O.