Details

Autor(en) / Beteiligte

• Ostapowicz, Thomas G.
• Schmitz, Marc
• Krystof, Monika
• Klankermayer, Jürgen
• Leitner, Walter

Titel

Carbon Dioxide as a C1 Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation

Ist Teil von

• Angewandte Chemie (International ed.), 2013-11, Vol.52 (46), p.12119-12123

Auflage

International ed. in English

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2013

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A happy marriage of two processes: An effective catalytic system was identified for the direct synthesis of carboxylic acids from non‐activated olefins or alcohols, CO2, and H2. Detailed analysis together with labeling studies indicated that the overall hydrocarboxylation of simple olefins results from a combination of the reverse water–gas shift (rWGS) reaction and a hydroxycarbonylation step, each promoted by a rhodium catalyst (see scheme).