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Functionalized carbon onions, detonation nanodiamond and mesoporous carbon as cathodes in Li-ion electrochemical energy storage devices
Ist Teil von
Carbon (New York), 2013-03, Vol.53, p.292-301
Ort / Verlag
Kidlington: Elsevier Ltd
Erscheinungsjahr
2013
Quelle
Access via ScienceDirect (Elsevier)
Beschreibungen/Notizen
Functionalization of carbon surface leads to the enhancement of ion storage capacity of carbon cathodes due to the additional pseudocapacitive reactions. In order to gain additional insights on the effects of the carbon specific surface area, porosity and oxygeni-containing functional groups on their electrochemical performance, we have investigated thick (>150μm) electrodes based on carbon onion nanopowder with and without functional groups present on carbon surface as well as nanodiamond soot and mesoporous activated carbon. Oxidation of carbon onion surface was found to result in a 2.4–2.8-fold increase in their specific capacitance. The larger average pore size and the absence of micropores in carbon nanoparticles based electrodes resulted in a better rate performance compared to that of mesoporous activated carbon. However, significant self-discharge was observed in all the oxidized samples. The low electrode density combined with limited overall charge storage capacity of carbon samples resulted in a volumetric capacity of less than 23mAhcm−3, compared to 450–700mAhcm−3 offered by state of the art high-density cathodes used in commercial Li-ion batteries. Even with further improvements, our estimations suggest that porous carbon cathodes will unlikely be able to offer more than 15% of the energy density of traditional cathodes.