Details

Autor(en) / Beteiligte

• Romanov, Alexey N.
• Veber, Alexander A.
• Fattakhova, Zukhra T.
• Usovich, Olga V.
• Haula, Elena V.
• Trusov, Lev. A.
• Kazin, Pavel E.
• Korchak, Vladimir N.
• Tsvetkov, Vladimir B.
• Sulimov, Vladimir B.

Titel

Subvalent bismuth monocation Bi+ photoluminescence in ternary halide crystals KAlCl4 and KMgCl3

Ist Teil von

• Journal of luminescence, 2013-02, Vol.134, p.180-183

Ort / Verlag

Elsevier B.V

Erscheinungsjahr

2013

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Monocation Bi+ isomorphically substitutes potassium in KAlCl4 and KMgCl3 chlorides. Having the unique 6p2 open-shell electronic configuration, Bi+ possesses a number of low-lying excited states, and displays broadband long-lived NIR photoluminescence in ternary chloride crystals. ► Monocation Bi+ can isomorphically substitute K+ in ternary chloride crystals. ► Bi+ doped ternary chlorides can be crystallized from Lewis acidic melts. ► Bi+ doped ternary chlorides possess broadband NIR luminescence.