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Formation of "Quasi" Contact or Solvent-separated Ion Pairs in the Local Environment of Probe Molecules Dissolved in Ionic Liquids
Ist Teil von
Chemphyschem, 2014-02, Vol.15 (2), p.265-270
Ort / Verlag
Weinheim: WILEY-VCH Verlag
Erscheinungsjahr
2014
Quelle
Access via Wiley Online Library
Beschreibungen/Notizen
The change from “quasi” contact to “quasi” solvent‐separated ion‐pair configuration in the local environment of a probe molecule in ionic liquids depends on the varying interaction strength of the chosen anions. The ion speciation in these Coulomb fluids could be shown by combining infrared spectroscopy, density functional theory calculations, and natural bond orbital analysis using a low‐self‐clustering probe molecule.
Configuration changes: The change from “quasi” contact to “quasi” solvent‐separated ion‐pair configuration in the local environment of a probe molecule in ionic liquids depends on the interaction strength of the chosen anions. Ion speciation in these Coulomb fluids is shown by combining infrared spectroscopy, density functional theory calculations, and natural bond orbital analysis using a low‐self‐clustering probe molecule.