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Improved photovoltaic performance of dye-sensitized solar cells (DSSCs) by Zn+Mg co-doped TiO(2) electrode
Ist Teil von
Electrochimica acta, 2013-04, Vol.95, p.48-53
Erscheinungsjahr
2013
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
Zn+Mg co-doped TiO(2) and the pure TiO(2) nanoparticles were prepared by the hydrothermal method. The pure TiO(2) and Zn+Mg co-doped TiO(2) were analyzed by X-ray photoelectron spectroscopy, X-ray diffraction, transmission electron miscroscopy, energy dispersive X-ray, UV-vis diffuse reflectance absorption spectra. Under a simulated solar light irradiation of 100 mWcm(-2), the cell based on doped TiO(2) electrode achieved a conversion efficiency of 9.07%, which is noticeably increased by 26.7% compared with undoped TiO(2) based DSSC (7.16%). The enhancement of conversion efficiency of the Zn+Mg co-doped TiO(2) was attributed to the positive shift of the flat band potentials and fast electron transport in TiO(2) films. The mechanism was suggested by intensity modulated photocurrent spectroscopy and intensity modulated photovoltage spectroscopy measurement.