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Five-Coordinate Silicon(II) Compounds with Si–M Bonds (M = Cr, Mo, W, Fe): Bis[N,N′‑diisopropylbenzamidinato(−)]silicon(II) as a Ligand in Transition-Metal Complexes
Reaction of the donor-stabilized silylene 1 with [Cr(CO)6], [Mo(CO)6], [W(CO)6], or [Fe(CO)5] leads to the formation of the transition-metal silylene complexes 2–5, which contain five-coordinate silicon(II) moieties with Si–M bonds (M = Cr, Mo, W, Fe). These compounds were characterized by NMR spectroscopic studies in the solid state and in solution and by crystal structure analyses. These experimental investigations were complemented by computational studies to gain insight into the bonding situation of 2–5. The nature of the Si–M bonds is best described as a single bond.
Sprache
Englisch
Identifikatoren
ISSN: 0020-1669
eISSN: 1520-510X
DOI: 10.1021/ic401954e
Titel-ID: cdi_proquest_miscellaneous_1443409185
Format
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