Details

Autor(en) / Beteiligte

• Sobczak, L.
• Brüggemann, O.
• Putz, R. F.

Titel

Polyolefin composites with natural fibers and wood-modification of the fiber/filler-matrix interaction

Ist Teil von

• Journal of applied polymer science, 2013-01, Vol.127 (1), p.1-17

Ort / Verlag

Hoboken: Wiley Subscription Services, Inc., A Wiley Company

Erscheinungsjahr

2013

Link zum Volltext

Quelle

Wiley Online Library All Journals

Beschreibungen/Notizen

• Numerous strategies to improve the fiber–matrix interaction in natural fiber composites (NFCs) and wood polymer composites (WPCs) have been proposed and investigated. We have reviewed literature on polyolefin‐based NFCs and WPCs to get an overview of the current state of the art of compatibilization methods. Those are classified in two categories here, namely fiber‐based strategies and matrix‐based strategies. Although this issue has been covered by several reviews before, as yet no work exists that is focused on polyolefin‐based NFCs and WPCs. Furthermore, a ranking of the compatibilization methods based on their effects on material properties such as tensile/flexural strength and modulus, impact strength and water absorption, allows for an assessment of the efficiency of the various methods. As to the fiber‐based strategies, silanes, maleated polyolefins (MA‐POs), mercerization and acetylation are most thoroughly investigated. Silanes are most effective judged by achievable material property improvements, allowing for increases in tensile and flexural strength of more than 100%. Among the matrix‐based strategies, MA‐POs and isocyanates are most prominent in the literature. The first class enables the more significant material improvements, with reported increases of tensile and flexural strength of 132% and 85%, respectively. While strengths can be enhanced by many compatibilization methods, moduli, and impact strength (notched in particular) are in most cases improved to a lesser degree or even reduced. Especially, the last point calls for further attention, because impact strength is still a weak point of NFCs and WPCs. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2013