Details

Autor(en) / Beteiligte

• Zhou, Feng
• Tan, Chen
• Tang, Jing
• Zhang, Yan-Yan
• Gao, Wei-Ming
• Wu, Hai-Hong
• Yu, Yi-Hua
• Zhou, Jian

Titel

Asymmetric Copper(I)-Catalyzed Azide–Alkyne Cycloaddition to Quaternary Oxindoles

Ist Teil von

• Journal of the American Chemical Society, 2013-07, Vol.135 (30), p.10994-10997

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2013

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• We report a highly enantioselective Cu(I)-catalyzed azide–alkyne cycloaddition via asymmetric desymmetrization of oxindole-based 1,6-heptadiynes, which furnishes quaternary oxindoles bearing a 1,2,3-triazole-containing moiety with 84–98% ee.