Details

Autor(en) / Beteiligte

• Chuang, Chun-Ju
• Yen, Ming-Liang
• Lai, Chien-Chen
• Liu, Yi-Hung
• Peng, Shie-Ming
• Chiu, Sheng-Hsien

Titel

Observation of face-to-face host-guest associated states prior to threading of dialkylammonium ions into the DB24C8-like openings of a molecular cage

Ist Teil von

• Chemical communications (Cambridge, England), 2013-05, Vol.49 (39), p.4199-4201

Ort / Verlag

England

Erscheinungsjahr

2013

Quelle

MEDLINE

Beschreibungen/Notizen

• The threading of bis(dialkylammonium) ions through the DB24C8-like openings of a molecular cage proceeds through a stepwise mechanism: formation of a face-to-face complex between the NH2(+) centers and the crown ether, significant dissociation of this complex, and passage of the terminus of the cation through the macrocycle.