Details

Autor(en) / Beteiligte

• Hayashi, Minoru
• Matsuura, Takashi
• Tanaka, Ippei
• Ohta, Hidetoshi
• Watanabe, Yutaka

Titel

Pd-Catalyzed P–C Cross-Coupling Reactions for Versatile Triarylphosphine Synthesis

Ist Teil von

• Organic letters, 2013-02, Vol.15 (3), p.628-631

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2013

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Practical and versatile syntheses of tertiary phosphine derivatives have been achieved by palladium-catalyzed deformylative P–C cross-coupling reactions of hydroxymethylphosphine derivatives. Sequential couplings of orthogonally protected precursors provide a simple and practical route toward a variety of tertiary phosphine derivatives having aryl substituents in any combination.