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The growth of AlN fibers using sublimation method was investigated in the temperature range from 1600 °C to 2000 °C. Large-scale AlN fibers are obtained with diameters from 100 nm to 50 μm and lengths up to several millimeters. The fiber morphology and growth direction are characterized by X-ray diffraction (XRD), field emission scanning electron microscope (SEM), high-resolution transmission electron microscopy (HRTEM), and Raman scattering. The fibers change from wire-like to prism-like in morphology and increase in diameter as rising temperatures, accompanying a transformation in axial direction from [10
] to [0001]. The transformation in the growth direction is discussed in terms of AlN structure and supersaturation of AlN gas species. These results provide useful information for controlling the growth of large-scale AlN fibers.