Details

Autor(en) / Beteiligte

• Ferrando-Soria, Jesús
• Serra-Crespo, Pablo
• de Lange, Martijn
• Gascon, Jorge
• Kapteijn, Freek
• Julve, Miguel
• Cano, Joan
• Lloret, Francesc
• Pasán, Jorge
• Ruiz-Pérez, Catalina
• Journaux, Yves
• Pardo, Emilio

Titel

Selective Gas and Vapor Sorption and Magnetic Sensing by an Isoreticular Mixed-Metal–Organic Framework

Ist Teil von

• Journal of the American Chemical Society, 2012-09, Vol.134 (37), p.15301-15304

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

2012

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A novel isoreticular oxamato-based manganese(II)–copper(II) open metal–organic framework H 2 O@ iso 1 featuring a pillared square/octagonal layer structure with alternating open and closed octagonal pores has been rationally prepared. The open-framework topology is responsible for a large selectivity in the separation of small gas (CO2 over CH4) and vapor molecules (CH3OH over CH3CN and CH3CH2OH). H 2 O@ iso 1 displays a long-range three-dimensional ferromagnetic ordering with a drastic variation of the critical temperature as a function of the guest molecule [T C < 2.0 K (CO 2 @ iso 1 and CH 4 @ iso 1) and T C = 6.5 (CH 3 OH@ iso 1) and 21.0 K (H 2 O@ iso 1)].