Details

Autor(en) / Beteiligte

• Bahoosh, S.G.
• Apostolov, A.T.
• Apostolova, I.N.
• Wesselinowa, J.M.

Titel

Theory of phonon properties in doped and undoped CuO nanoparticles

Ist Teil von

• Physics letters. A, 2012-07, Vol.376 (33), p.2252-2255

Ort / Verlag

Elsevier B.V

Erscheinungsjahr

2012

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• We have studied the phonon properties of CuO nanoparticles and have shown the importance of the anharmonic spin–phonon interaction. The Raman peaks of CuO nanoparticles shift to lower frequency and become broader as the particle size decreases in comparison with those of bulk CuO crystals owing to size effects. By doping with different ions, in dependence of their radius compared to the host ionic radius the phonon energies ω could be reduced or enhanced. The phonon damping is always enhanced through the ion doping effects. ► The phonon properties of CuO nanoparticles are studied using a miscroscopic model. ► The phonon energy decreases whereas the damping increases with decreasing of particle size. ► It is shown the importance of the anharmonic spin–phonon interaction. ► By doping with RE-ions the phonon energy is reduced, whereas with TM-ions it is enhanced. ► The phonon damping is always enhanced through the ion doping effects.