Angewandte Chemie International Edition, 2012-07, Vol.51 (31), p.7809-7811
International ed. in English, 2012
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Details
- Autor(en) / Beteiligte
- Titel
- Structure and Reactivity of an Iodosylarene Adduct of a Manganese(IV)-Salen Complex
- Ist Teil von
- Angewandte Chemie International Edition, 2012-07, Vol.51 (31), p.7809-7811
- Auflage
- International ed. in English
- Ort / Verlag
- Weinheim: WILEY-VCH Verlag
- Erscheinungsjahr
- 2012
- Quelle
- MEDLINE
- Beschreibungen/Notizen
- O transfer: The X‐ray crystal structure of an iodosylarene adduct of a manganese(IV)–salen complex shows bis‐iodosylarene coordination with a stepped conformation of the salen ligand. Spectroscopic characterization suggests that the complex maintains the same structure in solution. A reactivity study indicates that the manganese‐bound iodosylarene can directly transfer an oxygen atom to substrate.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1433-7851eISSN: 1521-3773DOI: 10.1002/anie.201202835Titel-ID: cdi_proquest_miscellaneous_1030076799
- Format
- –
- Schlagworte
- bioinorganic chemistry, Coordination Complexes - chemical synthesis, Coordination Complexes - chemistry, Crystallography, X-Ray, Ethylenediamines - chemistry, high-valent complexes, Iodobenzenes - chemistry, iodosylarenes, manganese, Manganese - chemistry, Models, Molecular, Molecular Structure, oxygenation