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Mo–N/Cu films were deposited on silicon and steel substrates by inductively coupled plasma sputtering using Mo–Cu alloy targets having different Cu concentrations. The structure and mechanical properties of the Mo–N/Cu films were investigated. The (200)-oriented
γ-Mo
2N–Cu films were obtained at a nitrogen flow rate higher than 1.5
sccm, whereas metallic films were deposited at a nitrogen flow rate lower than 1
sccm. Cu contents in the films increased from 3
at.% to 8
at.% with corresponding increase in Cu concentrations in the target from 5
at.% to 20
at.%. Hardness of the films varied between 19 and 35
GPa as the Cu concentration and nitrogen flow rate were changed. HRTEM and XPS analyses showed that Mo–N/Cu films consisted of
γ-Mo
2N grains lower than 10
nm in size and a copper amorphous phase. The minimum value of coefficient of friction (CoF) of the films was 0.17 when the film tested by alumina ball.